In general, we use:
at for a POINT
in for an ENCLOSED SPACE
on for a SURFACE
Use AT
a. with places on a page:
at the bottom of the page

b. in groups of people:
at the back of the class
at the front of the class
c. places/point:
at the bus-stop
at the door
ON
Use 'on' with surfaces:
on the ceiling / on the wall / on the floor
on the table
Use 'on' with small islands:
I stayed on Maui.
Use 'on' with directions:
on the left/on the right
straight on
IMPORTANT NOTES
In / at / on the corner
We say 'in the corner of a room', but 'at the corner (or 'on the corner') of a street'
In / at / on the front
We say 'in the front / in the back' of a car
We say 'at the front / at the back' of buildings / groups of people
We say 'on the front / on the back' of a piece of paper
Notice the use of the prepositions of place at, in and on in these standard expressions:

Activity
1. I am ____ work.
2. We are sitting ____ the park. It is a nice day.
3. My car is parked ____ the parking lot.
4. Our house is ____ the end of the street.
5. My sister lives ____ the 6th floor.
6. The books are ____ the bag.
7. The books are ____ the table.
8. There are a lot of books ____ the library.
9. I called their house, but nobody is ____ home.
10. There is a beautiful picture ____ the wall.
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